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Scientific article
English

One-Step Synthesis of Nitrogen-Containing Medium-Sized Rings via α-Imino Diazo Intermediates

Published inOrganic letters, vol. 16, no. 12, p. 3232-3235
Publication date2014
Abstract

Eight- and 9-membered dioxazocines and dioxazonines are readily synthesized starting from N-sulfonyl-1,2,3-triazoles in a single-step procedure. A perfect regioselectivity and generally good yields (up to 92%) are obtained under dirhodium catalysis using 1,3-dioxolane and 1,3-dioxane as solvents and reagents.

Citation (ISO format)
MEDINA, Florian, BESNARD, Céline, LACOUR, Jérôme. One-Step Synthesis of Nitrogen-Containing Medium-Sized Rings via α-Imino Diazo Intermediates. In: Organic letters, 2014, vol. 16, n° 12, p. 3232–3235. doi: 10.1021/ol5012532
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ISSN of the journal1523-7052
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Technical informations

Creation06/20/2014 10:20:00 AM
First validation06/20/2014 10:20:00 AM
Update time03/14/2023 9:22:25 PM
Status update03/14/2023 9:22:25 PM
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