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Enhancing ion-selective polymeric membrane electrodes by instrumental control

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Published in Trends in Analytical Chemistry. 2014, vol. 53, p. 98-105
Abstract This review aims to highlight a recent important direction to place ion-selective electrodes based on polymeric sensing materials under dynamic electrochemistry control. This allows one to design sensors with a range of improved characteristics. This review also showcases developments to achieve calibration-free ion-sensing strategies by using thin layer coulometry at ion-selective membranes. Finally, strategies to fabricate electrochemically-addressable ion-selective thin membrane layers are discussed, especially in view of realizing stripping ion-transfer voltammetric sensors.
Keywords Calibration-free measurementChronopotentiometryDynamic electrochemistryIon-selective electrodeIon speciationIon-transfer voltammetryLiquid–liquid electrochemistryPolymeric membrane electrodeStripping ion-transfer voltammetryThin-layer coulometry
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BAKKER, Eric. Enhancing ion-selective polymeric membrane electrodes by instrumental control. In: Trends in Analytical Chemistry, 2014, vol. 53, p. 98-105. https://archive-ouverte.unige.ch/unige:37924

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Deposited on : 2014-06-18

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