Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion

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Title		Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion
Authors		Bas, Delphine Buergi, Thomas Lacour, Jérôme Vachon, Jérôme Weber, Jacques
Published in		Chirality. 2005, vol. 17, no. S1, p. 143-148
Abstract		Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis of the [tetramethylammonium][-1] salt confirms the absolute configuration assignment obtained through X-ray crystallographic analysis of the parent cinchonidium salt. The structure, infrared, and vibrational circular dichroism (VCD) spectra derived from density functional theory (DFT) calculations are compared with experimental data.
Keywords		X-ray crystallography — CD properties — DFT — VCD
Identifiers		DOI: 10.1002/chir.20131 PMID: 15806572
Full text		Article (Published version) - Free access Other version: http://www3.interscience.wiley.com/cgi-bin/fulltext/110436114/PDFSTART
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie physique Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Research group		Groupe Weber
Citation (ISO format)		BAS, Delphine et al. Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion. In: Chirality, 2005, vol. 17, n° S1, p. 143-148. https://archive-ouverte.unige.ch/unige:3628