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Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion

Published inChirality, vol. 17, no. S1, p. 143-148
Publication date2005
Abstract

Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis of the [tetramethylammonium][-1] salt confirms the absolute configuration assignment obtained through X-ray crystallographic analysis of the parent cinchonidium salt. The structure, infrared, and vibrational circular dichroism (VCD) spectra derived from density functional theory (DFT) calculations are compared with experimental data.

Keywords
  • X-ray crystallography
  • CD properties
  • DFT
  • VCD
Research groups
Citation (ISO format)
BAS, Delphine et al. Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion. In: Chirality, 2005, vol. 17, n° S1, p. 143–148. doi: 10.1002/chir.20131
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accessLevelPublic
Identifiers
Journal ISSN1092-3276
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