Scientific article
Open access

Oxidation products of iminophosphorane and bis-iminophosphorane: An EPR study

Published inChemical physics letters, vol. 411, no. 1-3, p. 23-27
Publication date2005

Electrochemical oxidation of (C6H5)3Pdouble bond; length as m-dashN(C6H5) and (C6H5)3Pdouble bond; length as m-dashN(C6H5) leads to EPR spectra which reveal the dimeric structure of the resulting radical cation. In contrast to this behaviour, oxidation of bis-iminophosphorane leads to [(C6H5)3Pdouble bond; length as m-dashN(C6H4)N=P(C6H5)3]radical dot+: In these species the unpaired electron is delocalized on the N(C6H4)N moiety and the persistency of the radical depends upon the relative position of the two Pdouble bond; length as m-dashN bonds.

Research group
Citation (ISO format)
MATNI, Adil et al. Oxidation products of iminophosphorane and bis-iminophosphorane: An EPR study. In: Chemical physics letters, 2005, vol. 411, n° 1-3, p. 23–27. doi: 10.1016/j.cplett.2005.05.108
Main files (1)
Article (Published version)
ISSN of the journal0009-2614

Technical informations

Creation10/02/2009 3:19:01 PM
First validation10/02/2009 3:19:01 PM
Update time03/14/2023 3:15:41 PM
Status update03/14/2023 3:15:41 PM
Last indexation01/15/2024 7:04:04 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack