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An Experimental and Computational Study on Intramolecular Charge Transfer: A Tetrathiafulvalene Fused Dipyridophenazine Molecule

Published inChemistry, vol. 13, no. 13, p. 3804-3812
Publication date2007
Abstract

To study the electronic interactions in donor-acceptor (D-A) ensembles, D and A fragments are coupled in a single molecule. Specifically, a tetrathiafulvalene (TTF)-fused dipyrido[3,2-a:2,3-c]phenazine (dppz) compound having inherent redox centers has been synthesized and structurally characterized. Its electronic absorption, fluorescence emission, photoinduced intramolecular charge transfer, and electrochemical behavior have been investigated. The observed electronic properties are explained on the basis of density functional theory.

Keywords
  • Charge transfer
  • Donor-acceptor systems
  • Nitrogen heterocycles
  • Photophysical properties
  • Tetrathiafulvalene
Research group
Citation (ISO format)
JIA, Chunyang et al. An Experimental and Computational Study on Intramolecular Charge Transfer: A Tetrathiafulvalene Fused Dipyridophenazine Molecule. In: Chemistry, 2007, vol. 13, n° 13, p. 3804–3812. doi: 10.1002/chem.200601561
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ISSN of the journal0947-6539
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