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Title

An Experimental and Computational Study on Intramolecular Charge Transfer: A Tetrathiafulvalene Fused Dipyridophenazine Molecule

Authors
Jia, Chunyang
Liu, Shi-Xia
Tanner, Christian
Sanguinet, Lionel
Levillain, Eric
Leutwyler, Samuel
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Published in Chemistry - A European Journal. 2007, vol. 13, no. 13, p. 3804-3812
Abstract To study the electronic interactions in donor-acceptor (D-A) ensembles, D and A fragments are coupled in a single molecule. Specifically, a tetrathiafulvalene (TTF)-fused dipyrido[3,2-a:2,3-c]phenazine (dppz) compound having inherent redox centers has been synthesized and structurally characterized. Its electronic absorption, fluorescence emission, photoinduced intramolecular charge transfer, and electrochemical behavior have been investigated. The observed electronic properties are explained on the basis of density functional theory.
Keywords Charge transferDonor-acceptor systemsNitrogen heterocyclesPhotophysical propertiesTetrathiafulvalene
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Research group Groupe Hauser
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JIA, Chunyang et al. An Experimental and Computational Study on Intramolecular Charge Transfer: A Tetrathiafulvalene Fused Dipyridophenazine Molecule. In: Chemistry - A European Journal, 2007, vol. 13, n° 13, p. 3804-3812. https://archive-ouverte.unige.ch/unige:3597

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Deposited on : 2009-10-02

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