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The interaction between the spin transition and a crystallographic phase transition in the spin-crossover compound [Fe(bbtr)3](ClO4)2: Nucleation, formation of domains and fluctuations

Published inInorganica Chimica Acta, vol. 361, no. 12-13, p. 3616-3622
Publication date2008
Abstract

The thermal and the light-induced spin transition in [Fe(bbtr)3](ClO4)2 (bbtr = 1,4-di(1,2,3-triazol-1-yl)) as well as the high-spin?low-spin relaxation following the light-induced population of the high-spin state below the thermal transition temperature are discussed in relation to the accompanying crystallographic phase transition. The experimental data have exclusively been obtained using optical single crystal absorption spectroscopy.

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KRIVOKAPIC, Itana et al. The interaction between the spin transition and a crystallographic phase transition in the spin-crossover compound [Fe(bbtr)3](ClO4)2: Nucleation, formation of domains and fluctuations. In: Inorganica Chimica Acta, 2008, vol. 361, n° 12-13, p. 3616–3622. doi: 10.1016/j.ica.2008.03.064
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ISSN of the journal0020-1693
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