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Title

Bond Length and Bond Order in One of the Shortest Cr-Cr Bonds

Authors
Veryazov, Valera
Roos, Bjorn O.
Published in Inorganic Chemistry. 2008, vol. 47, no. 24, p. 11455-11457
Abstract Multiconfigurational quantum chemical calculations on the R-diimines dichromium compound confirm that the Cr-Cr bond, 1.80 A, is among the shortest Cr (I)-Cr (I) bonds. However, the bond between the two Cr atoms is only a quadruple bond rather than a quintuple bond. The reason why the bond is so short has to be attributed to the strain in the NCCN ligand moieties.
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Research group Groupe Gagliardi
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LA MACCHIA, Giovanni et al. Bond Length and Bond Order in One of the Shortest Cr-Cr Bonds. In: Inorganic Chemistry, 2008, vol. 47, n° 24, p. 11455-11457. https://archive-ouverte.unige.ch/unige:3563

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Deposited on : 2009-10-02

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