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Self-Assembly of Spheroidal Structures: The Coordination Chemistry of Pentacyanocyclopentadienide

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Published in Helvetica Chimica Acta. 2009, vol. 92, no. 11, p. 2480-2487
Abstract Modelling studies show that the anion pentacyanocyclopentadienide, 1, can complex linearly coordinating cations such as silver(I) and copper(I) to form a spheroidal complex [M30(1)12]18+ with minimum distortion. The anion 1 complexes transition metal ions to give species which appear to be polymers in the solid state. The structure of Ag(1) was determined by powder diffraction and shows a one-dimensional polymeric structure with three coordinate AgI and two CN functions of the ligand 1 non-coordinated. No evidence for the formation of the spheroidal complex was found.
Keywords Spheroidal structuresCyclopentadienide complexes, pentacyano-Silver complexesCopper complexes
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DA SILVA COSTA, Carlos et al. Self-Assembly of Spheroidal Structures: The Coordination Chemistry of Pentacyanocyclopentadienide. In: Helvetica Chimica Acta, 2009, vol. 92, n° 11, p. 2480-2487. https://archive-ouverte.unige.ch/unige:35437

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Deposited on : 2014-04-08

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