Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides

Hagemann, Hans-Rudolf; Tissot, Paul; Lovy, Dominique; Kubel, Frank; Bill, Hans

doi:10.1023/A:1010111323172

Scientific article

Open access

English

Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides

ContributorsHagemann, Hans-Rudolf; Tissot, Paul; Lovy, Dominique; Kubel, Frank; Bill, Hans

Published inJournal of thermal analysis and calorimetry, vol. 57, no. 1, p. 193-202

Publication date1999

Abstract

We have studied the solid-liquid equilibrium of the system Sr1–yBayFCl1–xBrx using DTA and X-ray diffraction techniques. The entire composition range in this system yields solid solutions which crystallize in the PbFCl (Matlockite) structure type. The melting points of the entire composition range have been parametrized (within 5°C rms error) using a biquadratic fit of the available data obtained by experiment and from the literature.

Keywords

Barium strontium fluorohalides
DTA
X-ray diffraction

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research group

Groupe Bill

Citation (ISO format)

HAGEMANN, Hans-Rudolf et al. Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides. In: Journal of thermal analysis and calorimetry, 1999, vol. 57, n° 1, p. 193–202. doi: 10.1023/A:1010111323172

Article (Published version)

Identifiers

PID : unige:3538
DOI : 10.1023/A:1010111323172

Commercial URLhttp://www.springerlink.com/content/m27342360mv37hm1/fulltext.pdf

ISSN of the journal1388-6150

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Study of the solid-liquid equilibrium in mixed alkaline earth fluorohalides

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