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Title

Bond-Stretch Isomerism: Trapped Isomeric Structures of Hexacoordinate Copper(II) Bispidine Chromophores along a Jahn-Teller Active Vibrational Coordinate

Authors
Comba, Peter
Kerscher, Marion
Pritzkow, Hans
Published in Angewandte Chemie: International Edition. 2003, vol. 42, no. 37, p. 4536-4540
Abstract The long and the short of it: Copper(II) complexes of the pentadentate bispidine ligands exist in two isomeric forms (see structure) with bond-length differences up to 0.5 Å. The stabilization of either isomer may be achieved by a variation of the substituent at N7.
Keywords Coordination chemistryCopperJahn-Teller effectsN ligands
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Structures
Research group Groupe Hauser
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COMBA, Peter et al. Bond-Stretch Isomerism: Trapped Isomeric Structures of Hexacoordinate Copper(II) Bispidine Chromophores along a Jahn-Teller Active Vibrational Coordinate. In: Angewandte Chemie: International Edition, 2003, vol. 42, n° 37, p. 4536-4540. https://archive-ouverte.unige.ch/unige:3511

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Deposited on : 2009-10-02

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