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Scientific article
English

Bond-Stretch Isomerism: Trapped Isomeric Structures of Hexacoordinate Copper(II) Bispidine Chromophores along a Jahn-Teller Active Vibrational Coordinate

Published inAngewandte Chemie, vol. 42, no. 37, p. 4536-4540
Publication date2003
Abstract

The long and the short of it: Copper(II) complexes of the pentadentate bispidine ligands exist in two isomeric forms (see structure) with bond-length differences up to 0.5 Å. The stabilization of either isomer may be achieved by a variation of the substituent at N7.

Keywords
  • Coordination chemistry
  • Copper
  • Jahn-Teller effects
  • N ligands
Research group
Citation (ISO format)
COMBA, Peter et al. Bond-Stretch Isomerism: Trapped Isomeric Structures of Hexacoordinate Copper(II) Bispidine Chromophores along a Jahn-Teller Active Vibrational Coordinate. In: Angewandte Chemie, 2003, vol. 42, n° 37, p. 4536–4540. doi: 10.1002/anie.200351900
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ISSN of the journal1433-7851
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