3,3',5,5' tetra(phosphaalkene) biphenyl : synthesis of a novel bicyclometalating bridging ligand and structure of its dipalladium complex

Jouaiti, Abdelaziz; Geoffroy, Michel; Bernardinelli, Gérald Hugues

doi:10.1016/S0040-4039(00)79169-6

Scientific article

English

3,3',5,5' tetra(phosphaalkene) biphenyl : synthesis of a novel bicyclometalating bridging ligand and structure of its dipalladium complex

ContributorsJouaiti, Abdelaziz; Geoffroy, Michel; Bernardinelli, Gérald Hugues

Published inTetrahedron letters, vol. 34, no. 21, p. 3413-3416

Publication date1993

Abstract

A biphenyl derivative bearing four phosphaalkene groups in positions 3,3',5,5' has been synthesized and is shown to be a bis-terdentate chelating agent; this novel bridging ligand forms a complex with two palladium ions and the crystal structure of this dinuclear species has been obtained.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Geoffroy

Citation (ISO format)

JOUAITI, Abdelaziz, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. 3,3′,5,5′ tetra(phosphaalkene) biphenyl : synthesis of a novel bicyclometalating bridging ligand and structure of its dipalladium complex. In: Tetrahedron letters, 1993, vol. 34, n° 21, p. 3413–3416. doi: 10.1016/S0040-4039(00)79169-6

Identifiers

PID : unige:3368
DOI : 10.1016/S0040-4039(00)79169-6

Additional URL for this publicationhttp://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6THS-42GDHH6-MJ-3&_cdi=5290&_user=779890&_orig=search&_coverDate=05%2F21%2F1993&_sk=999659978&view=c&wchp=dGLbVlW-zSkWA&md5=0db885d3f95a345195f94d62ec3a04b6&ie=/sdarticle.pdf

Journal ISSN0040-4039

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3,3',5,5' tetra(phosphaalkene) biphenyl : synthesis of a novel bicyclometalating bridging ligand and structure of its dipalladium complex

A biphenyl derivative bearing four phosphaalkene groups in positions 3,3',5,5' has been synthesized and is shown to be a bis-terdentate chelating agent; this novel bridging ligand forms a complex with two palladium ions and the crystal structure of this dinuclear species has been obtained.

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