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X-ray study on the lattice strains of ferroelectric iron iodine boracite Fe3B7O13I

Published inPhysical review. B, Condensed matter and materials physics, vol. 1, no. 9, p. 3801-3808
Publication date1970
Abstract

The accurate lattice parameters and the extremely small lattice strains of Fe I boracite, Fe3B7O13I, have been successfully measured over the paraelec. and the ferroelec. regions by using special x-ray diffraction methods. The spontaneous strains in the ferroelec. state could be sepd. into 2 parts, a linear strain (pure shear) and quadratic ones (electrostrictions). It is a conspicuous feature of the electromech. properties of Fe2B7O13I that the electrostrictions prevail over the linear strain induced through a torsional piezoelec. const. b36 of the paraelec. phase. The electrostrictive consts. are approx. 2 orders of magnitude larger than those of KH2PO4. Another phase transformation at a lower temp. was disclosed by the present diffractometry. At this temp., a special rhombohedral lattice is formed, and the piezo-elec. const. b36 vanishes.

Keywords
  • Electrostriction
  • Piezoelectricity
  • Lattice strain iron iodine boracite
Affiliation entities Not a UNIGE publication
Citation (ISO format)
KOBAYASHI, Jinzo et al. X-ray study on the lattice strains of ferroelectric iron iodine boracite Fe3B7O13I. In: Physical review. B, Condensed matter and materials physics, 1970, vol. 1, n° 9, p. 3801–3808.
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Article (Published version)
accessLevelPublic
Identifiers
  • PID : unige:32934
Journal ISSN1098-0121
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