Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

Li, Houhua; Mazet, Clement

doi:10.1021/ol403023x

Scientific article

English

Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

Contributors

Li, Houhua; Mazet, Clement

Published in

Organic letters, vol. 15, no. 24, p. 6170-6173

Publication date

2013

Abstract

The iridium-catalyzed diastereo- and regioselective isomerization of primary allylic alcohols using Crabtree's catalyst or sterically modified analogs is reported. The importance of the size of the substituents on either the substrates or the catalysts has been rationalized by linear free energy relationships.

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

UNIGE research groups

Groupe Mazet

Citation (ISO format)

LI, Houhua, MAZET, Clement. Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols. In: Organic letters, 2013, vol. 15, n° 24, p. 6170–6173. doi: 10.1021/ol403023x

Article (Published version)

Identifiers

PID : unige:32652
DOI : 10.1021/ol403023x

Journal ISSN

1523-7052

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Creation

20/12/2013 09:42:00

First validation

20/12/2013 09:42:00

Update

13/10/2025 23:09:36

Status update

14/03/2023 20:46:43

Last indexation

28/10/2025 23:01:22

Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

Contributors

Published in

Publication date

Abstract

UNIGE affiliation entities

UNIGE research groups

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation