Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

Li, Houhua; Mazet, Clement

doi:10.1021/ol403023x

Scientific article

English

Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

ContributorsLi, Houhua; Mazet, Clement

Published inOrganic letters, vol. 15, no. 24, p. 6170-6173

Publication date2013

Abstract

The iridium-catalyzed diastereo- and regioselective isomerization of primary allylic alcohols using Crabtree's catalyst or sterically modified analogs is reported. The importance of the size of the substituents on either the substrates or the catalysts has been rationalized by linear free energy relationships.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Research groups

Groupe Mazet

Citation (ISO format)

LI, Houhua, MAZET, Clement. Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols. In: Organic letters, 2013, vol. 15, n° 24, p. 6170–6173. doi: 10.1021/ol403023x

Article (Published version)

Identifiers

PID : unige:32652
DOI : 10.1021/ol403023x

Journal ISSN1523-7052

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Steric Parameters in the Ir-Catalyzed Regio- and Diastereoselective Isomerization of Primary Allylic Alcohols

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