UNIGE document Scientific Article
previous document  unige:3256  next document
add to browser collection
Title

Unusual regio- and enantioselective [1,2]-Stevens rearrangement of a spirobi[dibenzazepinium] cation

Authors
Gonçalves, Maria-Héléna
Published in Synlett. 2004, no. 9, p. 1565-1568
Abstract Highly symmetric spirobi[dibenzazepinium] cation 3 reacts with P4-t-Bu to form exclusively a ring-expanded tertiary amine; this unusual reactivity can be traced back to the geometry of the ylide.
Keywords AmmoniumRearrangementsRegioselectivityStereoselectivityYlides
Identifiers
Full text
Structures
Research group Groupe Weber
Citation
(ISO format)
VIAL, Laurent et al. Unusual regio- and enantioselective [1,2]-Stevens rearrangement of a spirobi[dibenzazepinium] cation. In: Synlett, 2004, n° 9, p. 1565-1568. https://archive-ouverte.unige.ch/unige:3256

259 hits

0 download

Update

Deposited on : 2009-09-21

Export document
Format :
Citation style :