Scientific article
English

Pseudo-binary Pb(Mg1/3Nb2/3)O3-PbO phase diagram and crystal growth of Pb(Mg1/3Nb2/3)O3 [PMN]

Published inMaterials research bulletin, vol. 25, no. 6, p. 739-748
Publication date1990
Abstract

A pseudo-binary phase diagram between the perovskite Pb(Mg1/3Nb2/3)O3 and PbO was established by DTA. The m.p. of PMN was found at 1320 Deg and the eutectic temp. at 830+-2 Deg with the eutectic compn. of 74%PbO/26%PMN (in wt%). On the basis of the detd. phase diagram, single crystals of the perovskite phase were grown by the high temp. soln. technique by using 30 wt.% PbO as solvent. The crystals show pseudo-cubic form with (100)cub growth steps or degenerated forms. Size (.apprx. 1cm) and quality of the obtained crystals are adequate for phys. characterizations.

Keywords
  • Crystal growth (of lead magnesium niobate, by high-temp. soln. method) lead magnesium niobate crystal growth
  • Phase diagram lead magnesium niobium oxide
Funding
  • Swiss National Science Foundation - 1989
Citation (ISO format)
YE, Zuo-Guang, TISSOT, Paul, SCHMID, Hans. Pseudo-binary Pb(Mg1/3Nb2/3)O3-PbO phase diagram and crystal growth of Pb(Mg1/3Nb2/3)O3 [PMN]. In: Materials research bulletin, 1990, vol. 25, n° 6, p. 739–748. doi: 10.1016/0025-5408(90)90202-D
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Article (Published version)
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Identifiers
Journal ISSN0025-5408
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