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Structural transitions in boracites: one or two order-parameters?

Published inJapanese journal of applied physics, vol. 24, p. 347-349
Publication date1985
Abstract

In light of the structural and dielec. data available for 23 boracites, a phenomenol. approach of the sequences of ferroelec.-ferroelastic phases obsd. in this family of compds. is proposed. It makes use of a single 6-dimensional order-parameter, in agreement with the theory of V. Dvorak and J. Petzelt (1971) and Yu. M. Gufan and V. P. Sakhnenko (1973) and in contrast to the 2-order-parameter model claimed by A. P. Levanyuk and D. G. Sannikov (1974, 5). A new interpretation is suggested for the temp. dependences of the polarization and dielec. permittivity, which involves 2 coupling terms, linear in the polarization components, and resp. quadratic and cubic in the order-parameter components.

Keywords
  • Ferroelasticity
  • Ferroelectricity
  • Dielectric constant and dispersion
  • Boracite structural transition
  • Ferroelastic transition boracite
  • Ferroelec transition boracite
NoteProceedings of the Sixth International Meeting on Ferroelectricity, Kobe 1985
Funding
  • Swiss National Science Foundation - 1984
Citation (ISO format)
TOLEDANO, Pierre et al. Structural transitions in boracites: one or two order-parameters? In: Japanese journal of applied physics, 1985, vol. 24, p. 347–349. doi: 10.7567/jjaps.24s2.347
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Article (Accepted version)
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Identifiers
Journal ISSN0021-4922
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