• Home
  1. Home
  2. Dynamic electrochemistry with ionophore based ion-selective membranes
Scientific article
OA Policy
English

Dynamic electrochemistry with ionophore based ion-selective membranes

Contributors

Crespo Paravano, Gaston Adrian; Bakker, Eric

Published in

RSC advances, vol. 3, no. 48, 25461

Publication date

2013

Abstract

This review outlines key principles and recent advances in the use of dynamic electrochemistry with polymeric liquid membranes. Ideally polarizable membranes are most attractive in fundamental studies of ion transfer and when the accumulation of the ion in the receiving phase is of key interest, for example in stripping ion transfer voltammetry. All solid-state membranes doped with conducting polymers have exhibited attractive low detection limit for hydrophilic ions. On the other hand, initially non-polarized interfaces are most useful when one aims to effect a concentration change of an ionic species in the sample phase. Conveniently, these types of membranes can be interrogated with potentiometry and sequentially with dynamic techniques such as chronopotentiometry. This can be used to obtain speciation information as they allow one, in principle, to assess total labile and free ion concentrations in the same experiment. A number of electrochemical techniques have been reported and include controlled potential techniques such as cyclic voltammetry, normal pulse voltammetry, stripping voltammetry and thin layer coulometry as well as current controlled ones such as pulsed chronopotentiometry and flash chronopotentiometry. All of these techniques have their purpose and strength.

UNIGE affiliation entities

UNIGE research groups

Citation (ISO format)

CRESPO PARAVANO, Gaston Adrian, BAKKER, Eric. Dynamic electrochemistry with ionophore based ion-selective membranes. In: RSC advances, 2013, vol. 3, n° 48, p. 25461. doi: 10.1039/c3ra43751e

Main files (1)

Article (Published version)

Identifiers

Additional URL for this publication

http://xlink.rsc.org/?DOI=c3ra43751e

Journal ISSN

2046-2069
707views
1237downloads

Technical informations

Creation

27/11/2013 15:22:00

First validation

27/11/2013 15:22:00

Update

14/03/2023 20:38:57

Status update

14/03/2023 20:38:57

Last indexation

30/10/2024 15:05:43
All rights reserved by Archive ouverte UNIGE and the University of Geneva
OpenAIRE Indexed & Validated