Scientific article

Chemical and x-ray studies of ferroelectric domains in KNiPO4

Published inFerroelectrics, vol. 172, no. 1-4, p. 193-199
Publication date1995

Crystals of KNiPO4 have space group Pna21 at room temp. (a 8.6358(4), b 9.2594(5) and c 4.9096(3) .ANG.). This compd. has two structural phase transitions, at 485 Deg and 580 Deg. Ferroelec. 180 Deg domains are revealed by chem. etching with a 0.1M HCl soln. on {001} cuts. A single domain was cut from an etched crystal and an x-ray study of the abs. structure showed that the (001) facets are preferentially dissolved by the etchant. Another crystal having the two ferroelec. domain orientations in a ratio 31.3:68.7 was also cut from the same etched sample and studied by x-ray diffraction. The abs. structure parameter xabs, available in the Xtal 3.2 program was refined together with the other variables. This parameter gives the ratio of the crystal which has its abs. structure reversed with respect to the model. A final value of xabs = 33.2(1.8)% for the twinned crystal was found. [on SciFinder (R)]

  • Ferroelectric domains
  • X-ray diffraction
  • KNiP04
  • Chemical etching
  • Absolute structure
  • Swiss National Science Foundation - 1994
Citation (ISO format)
LUJAN PEREZ, Marcos Luis, KUBEL, Frank, SCHMID, Hans. Chemical and x-ray studies of ferroelectric domains in KNiPO<sub>4</sub>. In: Ferroelectrics, 1995, vol. 172, n° 1-4, p. 193–199.
Main files (1)
Article (Published version)
  • PID : unige:31329
ISSN of the journal0015-0193

Technical informations

Creation11/08/2013 7:06:00 AM
First validation11/08/2013 7:06:00 AM
Update time03/14/2023 8:38:11 PM
Status update03/14/2023 8:38:11 PM
Last indexation01/16/2024 8:14:22 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack