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An O2- molecule ion in CaF2: Structure and dynamical features

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Published in Journal of Chemical Physics. 1979, vol. 70, no. 1, p. 277-283
Abstract This experimental study reports EPR and ENDOR results of an O<sup> - </sup><sub>2</sub> molecule ion in natural yellow fluorites. The O<sup> - </sup><sub>2</sub> is associated with a sodium neighbor and a calcium neighbor. This cluster performs a rapid switching movement between energetically equivalent positions. The resulting dynamical features in the EPR spectrum are investigated with the aid of the stochastic Liouville equation.
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Research group Groupe Bill
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BILL, Hans. An O2- molecule ion in CaF2: Structure and dynamical features. In: Journal of Chemical Physics, 1979, vol. 70, n° 1, p. 277-283. https://archive-ouverte.unige.ch/unige:3132

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Deposited on : 2009-09-21

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