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Investigation of sulfur molecular paramagnetic centers in SrCl2

Siebenthal, Jean-Marc de
Published in Physica Status Solidi. B. 1979, vol. 91, no. 2, p. 479-486
Abstract S2 and S3 centers in SrCl2 single crystals are observed. The underlying experimental investigation is carried out by EPR, Raman, and optical absorption spectroscopy. The S centers show dynamical features in their EPR spectra. The temperature dependence of these spectra is compared with the results of the Kubo line shape theory. This enables to identify the motion as a thermally activated reorientation of the center between two equivalent equilibrium positions.
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Research group Groupe Bill
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SIEBENTHAL, Jean-Marc de, BILL, Hans. Investigation of sulfur molecular paramagnetic centers in SrCl2. In: Physica Status Solidi. B, 1979, vol. 91, n° 2, p. 479-486. https://archive-ouverte.unige.ch/unige:3130

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Deposited on : 2009-09-21

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