Scientific article

Far-infrared spectra of well-defined thiolate-protected gold clusters

Published inPCCP. Physical chemistry chemical physics, vol. 15, no. 45, p. 19561-19565
Publication date2013

The far infrared spectra of a series of well-defined gold clusters covered by 2-phenylethanetiolate were studied. The spectra of the cluster are different but the differences are subtle. The Au-S stretching vibrations give rise to bands around 300 cm-1 and below. The relative intensity of these bands changes but they shift only slightly for different clusters. A low-frequency band was identified that is sensitive to the conformation (trans / gauche) of the 2-phenylethanetiolate ligand.

Research group
Citation (ISO format)
DOLAMIC, Igor, VARNHOLT, Birte, BUERGI, Thomas. Far-infrared spectra of well-defined thiolate-protected gold clusters. In: PCCP. Physical chemistry chemical physics, 2013, vol. 15, n° 45, p. 19561–19565. doi: 10.1039/c3cp53845a
Main files (1)
Article (Published version)
ISSN of the journal1463-9076

Technical informations

Creation11/22/2013 8:43:00 AM
First validation11/22/2013 8:43:00 AM
Update time03/14/2023 8:37:58 PM
Status update03/14/2023 8:37:58 PM
Last indexation01/16/2024 8:13:18 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack