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Far-infrared spectra of well-defined thiolate-protected gold clusters

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Published in Physical Chemistry Chemical Physics. 2013, vol. 15, no. 45, p. 19561-19565
Abstract The far infrared spectra of a series of well-defined gold clusters covered by 2-phenylethanetiolate were studied. The spectra of the cluster are different but the differences are subtle. The Au-S stretching vibrations give rise to bands around 300 cm-1 and below. The relative intensity of these bands changes but they shift only slightly for different clusters. A low-frequency band was identified that is sensitive to the conformation (trans / gauche) of the 2-phenylethanetiolate ligand.
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Other version: http://xlink.rsc.org/?DOI=c3cp53845a
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Research group Groupe Bürgi
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DOLAMIC, Igor, VARNHOLT, Birte, BUERGI, Thomas. Far-infrared spectra of well-defined thiolate-protected gold clusters. In: Physical Chemistry Chemical Physics, 2013, vol. 15, n° 45, p. 19561-19565. https://archive-ouverte.unige.ch/unige:31280

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Deposited on : 2013-11-22

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