The electronic structure of CrO43- as studied by EPR in K2SO4 single crystals

Ravi Sekhar, Y.; Bill, Hans

doi:10.1016/0009-2614(82)83426-X

Article scientifique

Anglais

The electronic structure of CrO43- as studied by EPR in K2SO4 single crystals

Contributeurs/tricesRavi Sekhar, Y.; Bill, Hans

Publié dansChemical physics letters, vol. 92, no. 4, p. 349-352

Date de publication1982

Résumé

EPR and ENDOR investigations are carried out on irradiated K2SO4 crystals doped with CrO42− ions. They indicate the formation of CrO43− centers interacting with a nearby proton. The identification of the CrO43− centers is based on their g values, the orientation of the g tensor and the symmetry requirements. The results are compared with related studies on MnO42− in K2SO4 and K2CrO4 hosts.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Groupe de recherche

Groupe Bill

Citation (format ISO)

RAVI SEKHAR, Y., BILL, Hans. The electronic structure of CrO43- as studied by EPR in K2SO4 single crystals. In: Chemical physics letters, 1982, vol. 92, n° 4, p. 349–352. doi: 10.1016/0009-2614(82)83426-X

Identifiants

PID : unige:3120
DOI : 10.1016/0009-2614(82)83426-X

ISSN du journal0009-2614

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The electronic structure of CrO43- as studied by EPR in K2SO4 single crystals

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