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Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy

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Deyhimi, Farzad
Published in Journal of Solid State Chemistry. 1982, vol. 43, no. 2, p. 181-189
Abstract A family of molecular centers of the type (RO2M)2+ is shown to exist in the alkaline earth fluorides MF2 (M = Ca, Sr, Ba) doped with R = Sc, Y, Lu, Ho when these crystals have been hydrolyzed and subsequently X-rayed. The centers were identified with the aid of Raman spectroscopy and, in the past, with electron paramagnetic resonance (EPR).
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Research group Groupe Bill
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DEYHIMI, Farzad, BILL, Hans. Analogs of the Rose center in the alkaline earth fluorides: Production by hydrolysis and identification by Raman spectroscopy. In: Journal of Solid State Chemistry, 1982, vol. 43, n° 2, p. 181-189. https://archive-ouverte.unige.ch/unige:3116

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Deposited on : 2009-09-21

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