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Scientific article
English

A single crystal electron spin resonance study of a nitroxide radical exhibiting hyperfine coupling with a β-proton

Contributors

Berclaz, Théo; Geoffroy, Michel; Lucken, Edwin-Anthony; Tronchet, Jean Marcel Julien

Published in

Journal of the Chemical Society. Perkin transactions II, vol. 44, no. 2, p. 127-130

Publication date

1983

Abstract

Crystallization of 2-glycosyl-1,3-dihydroxy-4,4,5,5-tetramethylimidazolidine under aerobic conditions gives rise to single crystals which contain a small amount of the 2-glycosyl-3-hydroxyimidazolidin-1-oxyl radical. Hyperfine coupling tensors with the nitroxide nitrogen, a -proton, and a -nitrogen are obtained. The anisotropic coupling constants for the -proton are larger than those calculated for a nitroxide in a planar conformation.

UNIGE affiliation entities

UNIGE research groups

Citation (ISO format)

BERCLAZ, Théo et al. A single crystal electron spin resonance study of a nitroxide radical exhibiting hyperfine coupling with a β-proton. In: Journal of the Chemical Society. Perkin transactions II, 1983, vol. 44, n° 2, p. 127–130. doi: 10.1039/P29830000127

Main files (1)

Article (Published version)

Identifiers

Journal ISSN

0300-9580
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Technical informations

Creation

21/09/2009 16:20:37

First validation

21/09/2009 16:20:37

Update

04/04/2025 13:02:20

Status update

16/12/2024 14:18:19

Last indexation

04/04/2025 13:04:13
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