E[circle times operator]ε-type Jahn-Teller effect of ReO42- in KBr crystals: an EPR study
|Published in||Journal of Physics. C, Solid State Physics. 1983, vol. L16, no. 24, p. 889-894|
|Abstract||EPR experiments have been carried out on irradiated KBr crystals doped with ReO4- ions at 4.2K. They indicate the formation of ReO42- (5d1, 2E ground state) subjected to an E(X) epsilon -type Jahn-Teller distortion. Uniaxial stress experiment show that the ReO42- ion reorientates locally and the spin Hamiltonian parameters are unaltered by the application of the stress. A quadratic stress coupling term cannot be neglected. A model based on the approach of M.C.M. O'Brien is proposed to explain the experimental results.|
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|Research group||Groupe Bill|
|BILL, Hans, RAVI SEKHAR, Y. E[circle times operator]ε-type Jahn-Teller effect of ReO42- in KBr crystals: an EPR study. In: Journal of Physics. C, Solid State Physics, 1983, vol. L16, n° 24, p. 889-894. doi: 10.1088/0022-3719/16/24/004 https://archive-ouverte.unige.ch/unige:3110|