Endor study of Gd3+ in Cs2NaYCl6

Bill, Hans; Magne, Georges; Güdel, Hans-Ulrich; Neuenschwander, Klaus

doi:10.1016/0009-2614(84)80206-7

Scientific article

Letter

English

Endor study of Gd³⁺ in Cs₂NaYCl₆

ContributorsBill, Hans; Magne, Georges; Güdel, Hans-Ulrich; Neuenschwander, Klaus

Published inChemical physics letters, vol. 104, no. 2-3, p. 258-262

Publication date1984

Abstract

Crystals of Cs₂NaYCl₆ doped with Gd³⁺ were investigated using EPR and ENDOR spectroscopy. The Gd³⁺ site symmetry at 4.2 K is found to be cubic. The lattice does not undergo a structural phase change between 300 and 4.2 K. Literature ENDOR data for Cs₂NaYCl₆ doped with Ce³⁺ are re-interpreted.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Bill

Citation (ISO format)

BILL, Hans et al. Endor study of Gd³⁺ in Cs₂NaYCl₆. In: Chemical physics letters, 1984, vol. 104, n° 2-3, p. 258–262. doi: 10.1016/0009-2614(84)80206-7

Article (Published version)

Identifiers

PID : unige:3108
DOI : 10.1016/0009-2614(84)80206-7

Journal ISSN0009-2614

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Endor study of Gd3+ in Cs2NaYCl6

Crystals of Cs2NaYCl6 doped with Gd3+ were investigated using EPR and ENDOR spectroscopy. The Gd3+ site symmetry at 4.2 K is found to be cubic. The lattice does not undergo a structural phase change between 300 and 4.2 K. Literature ENDOR data for Cs2NaYCl6 doped with Ce3+ are re-interpreted.

Technical informations

Endor study of Gd³⁺ in Cs₂NaYCl₆