Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1-xFex(ptz)6(BF4)2 spin-crossover systems
|Published in||Chemical Physics Letters. 1986, vol. 124, no. 6, p. 543-548|
|Abstract||Fe(ptz)6(BF4)2 (ptz = 1-propyltetrazole) is an iron(II) spin-crossover system which shows light-induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn1−xFex(ptz)6(BF4)2 (x ≈ 0.1) and is therefore basically a single-ion property, and (b) that the phenomenon is reversible. The efficiency of the light-induced spin crossover is of the order of 0.5% in the forward direction and 0.1% in the reverse direction.|
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|Research group||Groupe Hauser|
|HAUSER, Andreas. Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1-xFex(ptz)6(BF4)2 spin-crossover systems. In: Chemical Physics Letters, 1986, vol. 124, n° 6, p. 543-548. https://archive-ouverte.unige.ch/unige:3094|