UNIGE document Scientific Article
previous document  unige:3094  next document
add to browser collection
Title

Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1-xFex(ptz)6(BF4)2 spin-crossover systems

Author
Published in Chemical Physics Letters. 1986, vol. 124, no. 6, p. 543-548
Abstract Fe(ptz)6(BF4)2 (ptz = 1-propyltetrazole) is an iron(II) spin-crossover system which shows light-induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn1−xFex(ptz)6(BF4)2 (x ≈ 0.1) and is therefore basically a single-ion property, and (b) that the phenomenon is reversible. The efficiency of the light-induced spin crossover is of the order of 0.5% in the forward direction and 0.1% in the reverse direction.
Identifiers
Full text
This document has no fulltext available yet, but you can contact its author by using the form below.
Structures
Research group Groupe Hauser
Citation
(ISO format)
HAUSER, Andreas. Reversibility of light-induced excited spin state trapping in the Fe(ptz)6(BF4)2, and the Zn1-xFex(ptz)6(BF4)2 spin-crossover systems. In: Chemical Physics Letters, 1986, vol. 124, n° 6, p. 543-548. https://archive-ouverte.unige.ch/unige:3094

194 hits

0 download

Update

Deposited on : 2009-09-21

Export document
Format :
Citation style :