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Title

Single crystal x-ray study of rhombohedral cobalt-fluorine (OH) boracite

Authors
Berset, Guy
Depmeier, Wulf
Published in Ferroelectrics. 1984, vol. 56, no. 1, p. 13-16
Abstract Co3B7O13F(OH), space group R3c, arh =12.0738(6) Å, αrh = 89.59(5), Z=6, residual R=0.059 (1970 reflections, 78 parameters). In contrast to cubic boracites the structure contains strong metal-halogen bonds (d(Co—F)=2.169(3) Å). Some of the oxygen-boron bonds are considerably weakened.
Keywords Crystal structureMolecular structure (of cobalt fluorine hydroxy boracite)
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Project FNS: 1983
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BERSET, Guy et al. Single crystal x-ray study of rhombohedral cobalt-fluorine (OH) boracite. In: Ferroelectrics, 1984, vol. 56, n° 1, p. 13-16. https://archive-ouverte.unige.ch/unige:30828

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Deposited on : 2013-10-31

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