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Scientific article
English

α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides

Published inChemistry - an Asian journal, vol. 8, no. 11, p. 2579-2583
Publication date2013
Abstract

The selective α-arylation and α-arylative esterification of linear and branched aldehydes is reported for a variety of bromoarenes. The acylation of aryl bromides can be achieved with linear aldehydes (see scheme). All these transformations were performed with a single [(N-heterocyclic carbene)Pd] catalyst through adjustment of the stoichiometry of the reagents and the appropriate base.

Keywords
  • Acylation
  • Arylation
  • Cross-coupling
  • Esterification
  • Palladium
Citation (ISO format)
NAREDDY, Pradeep, MAZET, Clement. α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides. In: Chemistry - an Asian journal, 2013, vol. 8, n° 11, p. 2579–2583. doi: 10.1002/asia.201300724
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ISSN of the journal1861-471X
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Creation10/29/2013 10:12:00 AM
First validation10/29/2013 10:12:00 AM
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