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α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides

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Published in Chemistry (Asian Journal). 2013, vol. 8, no. 11, p. 2579-2583
Abstract The selective α-arylation and α-arylative esterification of linear and branched aldehydes is reported for a variety of bromoarenes. The acylation of aryl bromides can be achieved with linear aldehydes (see scheme). All these transformations were performed with a single [(N-heterocyclic carbene)Pd] catalyst through adjustment of the stoichiometry of the reagents and the appropriate base.
Keywords AcylationArylationCross-couplingEsterificationPalladium
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Other version: http://doi.wiley.com/10.1002/asia.201300724
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NAREDDY, Pradeep, MAZET, Clement. α-Arylation, α-Arylative Esterification, or Acylation: A Stoichiometry-Dependent Trichotomy in the Pd-Catalyzed Cross-Coupling between Aldehydes and Aryl Bromides. In: Chemistry (Asian Journal), 2013, vol. 8, n° 11, p. 2579-2583. https://archive-ouverte.unige.ch/unige:30785

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Deposited on : 2013-10-29

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