en
Scientific article
English

Free Energy Dependence of the Ion Yield Of Photoinduced Electron-Transfer Reactions in Solution

Published inHelvetica chimica acta, vol. 71, no. 1, p. 93-99
Publication date1988
Abstract

A study of photo-induced electron-transfer reactions in MeCN with 9,10-dicyanoanthracene as acceptor and 21 electron donors with transient photoconductivity measurements is reported. The free-ion yield and the rate constant of back electron transfer are determined. For exergonic reactions, the Marcus-inverted region is observed. The fit with the theory is best, when a nearly solvent-independent Coulomb term is used in the calculation of the energy balance.

Research group
Citation (ISO format)
VAUTHEY, Eric, SUPPAN, Paul, HASELBACH, Edwin. Free Energy Dependence of the Ion Yield Of Photoinduced Electron-Transfer Reactions in Solution. In: Helvetica chimica acta, 1988, vol. 71, n° 1, p. 93–99. doi: 10.1002/hlca.19880710111
Identifiers
ISSN of the journal0018-019X
588views
0downloads

Technical informations

Creation09/21/2009 4:20:04 PM
First validation09/21/2009 4:20:04 PM
Update time03/14/2023 3:13:25 PM
Status update03/14/2023 3:13:24 PM
Last indexation05/02/2024 11:17:31 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack