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Free Energy Dependence of the Ion Yield Of Photoinduced Electron-Transfer Reactions in Solution

Authors
Suppan, Paul
Haselbach, Edwin
Published in Helvetica Chimica Acta. 1988, vol. 71, no. 1, p. 93-99
Abstract A study of photo-induced electron-transfer reactions in MeCN with 9,10-dicyanoanthracene as acceptor and 21 electron donors with transient photoconductivity measurements is reported. The free-ion yield and the rate constant of back electron transfer are determined. For exergonic reactions, the Marcus-inverted region is observed. The fit with the theory is best, when a nearly solvent-independent Coulomb term is used in the calculation of the energy balance.
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Research group Groupe Vauthey
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VAUTHEY, Eric, SUPPAN, Paul, HASELBACH, Edwin. Free Energy Dependence of the Ion Yield Of Photoinduced Electron-Transfer Reactions in Solution. In: Helvetica Chimica Acta, 1988, vol. 71, n° 1, p. 93-99. https://archive-ouverte.unige.ch/unige:3073

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Deposited on : 2009-09-21

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