EPR and optical investigation of thermally treated NaF: Cu single crystals

Minner, Edith; Bill, Hans

doi:10.1016/0009-2614(90)85548-Q

Scientific article

English

EPR and optical investigation of thermally treated NaF: Cu single crystals

ContributorsMinner, Edith; Bill, Hans

Published inChemical physics letters, vol. 175, no. 3, p. 231-236

Publication date1990-12-07

Abstract

Though Cu⁺ is thermodynamically unstable in NaF, it has been introduced into this host crystal. The initial stage of its conversion into Cu⁰ and Cu²⁺ has been investigated. EPR of copper clusters and of a tetragonal Cu²⁺-NNN Schottky-vacancy complex was observed. An optical absorption band associated with this latter one was found.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Bill

Citation (ISO format)

MINNER, Edith, BILL, Hans. EPR and optical investigation of thermally treated NaF: Cu single crystals. In: Chemical physics letters, 1990, vol. 175, n° 3, p. 231–236. doi: 10.1016/0009-2614(90)85548-Q

Article (Published version)

Identifiers

PID : unige:3058
DOI : 10.1016/0009-2614(90)85548-Q

Journal ISSN0009-2614

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EPR and optical investigation of thermally treated NaF: Cu single crystals

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