Scientific article
English

Electron capture by trivalent phosphorus compounds: A single crystal ESR study of the chlorodithiaphospholane anion

Published inChemical physics letters, vol. 167, no. 5, p. 460-466
Publication date1990
Abstract

The 2-chloro-1,3,2-dithiaphospholane anion has been trapped in an X-irradiated single crystal of 1. The anion has been identified by comparing its 31P and 35Cl hyperfine tensors with the corresponding couplings obtained from ab initio calculations on H2PCl−. and PCl3−.. The structure of R2PCl− is discussed. Increasing the temperature causes the dissociation reaction to occur, and the phosphinyl radical has been observed after annealing at 220 K.

Research groups
Citation (ISO format)
CATTANI-LORENTE, Maria, GEOFFROY, Michel. Electron capture by trivalent phosphorus compounds: A single crystal ESR study of the chlorodithiaphospholane anion. In: Chemical physics letters, 1990, vol. 167, n° 5, p. 460–466. doi: 10.1016/0009-2614(90)85031-7
Identifiers
Journal ISSN0009-2614
493views
0downloads

Technical informations

Creation21/09/2009 16:19:49
First validation21/09/2009 16:19:49
Update time14/03/2023 15:13:21
Status update14/03/2023 15:13:21
Last indexation29/10/2024 12:08:33
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack