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Title

Electron capture by trivalent phosphorus compounds: A single crystal ESR study of the chlorodithiaphospholane anion

Authors
Cattani-Lorente, Maria
Published in Chemical Physics Letters. 1990, vol. 167, no. 5, p. 460-466
Abstract The 2-chloro-1,3,2-dithiaphospholane anion has been trapped in an X-irradiated single crystal of 1. The anion has been identified by comparing its 31P and 35Cl hyperfine tensors with the corresponding couplings obtained from ab initio calculations on H2PCl−. and PCl3−.. The structure of R2PCl− is discussed. Increasing the temperature causes the dissociation reaction to occur, and the phosphinyl radical has been observed after annealing at 220 K.
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Research group Groupe Geoffroy
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CATTANI-LORENTE, Maria, GEOFFROY, Michel. Electron capture by trivalent phosphorus compounds: A single crystal ESR study of the chlorodithiaphospholane anion. In: Chemical Physics Letters, 1990, vol. 167, n° 5, p. 460-466. https://archive-ouverte.unige.ch/unige:3057

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Deposited on : 2009-09-21

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