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Limited access to UNIGEOther version: http://doi.wiley.com/10.1002/ejoc.201300971
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Titles listConstruction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis
Titles listConstruction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis
Scientific Article
unige:30348 
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Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis |
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| Published in | European Journal of Organic Chemistry. 2013, vol. 2013, no. 29, p. 6710-6721 | |
| Abstract | A new approach to highly enantioenriched cyclic compounds (up to 98 % ee) has been developed by using ω-ethylenic allylic substrates in a one-pot asymmetric allylic alkylation and ring-closing metathesis sequence. The starting compounds are synthetic equivalents of cyclic allylic substrates. The method is exemplified with both Cu and Ir catalysts, and chiral phosphoramidite ligands. | |
| Keywords | Asymmetric synthesis — Allylic alkylation — Cyclization — Metathesis — Copper — Iridium | |
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Article (Published version) (895 Kb) - Limited access to UNIGE Other version: http://doi.wiley.com/10.1002/ejoc.201300971 |
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| Structures | ||
| Citation (ISO format) | GIACOMINA, Francesca, ALEXAKIS, Alexandre. Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis. In: European Journal of Organic Chemistry, 2013, vol. 2013, n° 29, p. 6710-6721. https://archive-ouverte.unige.ch/unige:30348 |
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