The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile

Vauthey, Eric; Pilloud, Denis; Haselbach, Edwin; Suppan, Paul; Jacques, Philippe

doi:10.1016/0009-2614(93)89298-V

Scientific article

English

The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile

ContributorsVauthey, Eric

; Pilloud, Denis; Haselbach, Edwin; Suppan, Paul; Jacques, Philippe

Published inChemical physics letters, vol. 215, no. 1-3, p. 264-268

Publication date1993

Abstract

A detailed study of the separation efficiency in the photoinduced electron transfer reaction between 9,10-dicyanoanthracene and biphenyl in acetonitrile is presented. Both transient absorption and photoconductivity indicate a separation efficiency of about 0.4. This value is in discrepancy with two of three previously reported efficiencies. The problems arising with too large donor concentrations and with the use of a secondary donor to determine the separation efficiency are discussed.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Vauthey

Citation (ISO format)

VAUTHEY, Eric et al. The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile. In: Chemical physics letters, 1993, vol. 215, n° 1-3, p. 264–268. doi: 10.1016/0009-2614(93)89298-V

Identifiers

PID : unige:3019
DOI : 10.1016/0009-2614(93)89298-V

Journal ISSN0009-2614

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The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile

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