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Title

The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile

Authors
Pilloud, Denis
Haselbach, Edwin
Suppan, Paul
Jacques, Philippe
Published in Chemical Physics Letters. 1993, vol. 215, no. 1-3, p. 264-268
Abstract A detailed study of the separation efficiency in the photoinduced electron transfer reaction between 9,10-dicyanoanthracene and biphenyl in acetonitrile is presented. Both transient absorption and photoconductivity indicate a separation efficiency of about 0.4. This value is in discrepancy with two of three previously reported efficiencies. The problems arising with too large donor concentrations and with the use of a secondary donor to determine the separation efficiency are discussed.
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Research group Groupe Vauthey
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VAUTHEY, Eric et al. The Reliability of Free Ion Yield in Photoinduced Electron Transfer Reactions. The Model System 9,10-Dicyanoanthracene/Biphenyl in acetonitrile. In: Chemical Physics Letters, 1993, vol. 215, n° 1-3, p. 264-268. https://archive-ouverte.unige.ch/unige:3019

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Deposited on : 2009-09-21

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