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Title

Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition

Authors
Magrez-Chiquet, Magaly
Morin, Marie S. T.
Wencel-Delord, Joanna
Drissi Amraoui, Sammy
Baslé, Olivier
Crévisy, Christophe
Mauduit, Marc
Published in Chemistry - A European Journal. 2013, vol. 19, no. 41, p. 13663-13667
Abstract C-C coupling: DiPPAM 1 and BINAP 2 ligands led to divergent behaviors in the asymmetric conjugate addition (ACA) of dialkylzinc reagents to linear aryldienones, which were applied to the development of a highly selective sequential asymmetric 1,6/1,4-ACA process.
Keywords Asymmetric synthesisC—C couplingMichael reactionStereoselective catalysis
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Other version: http://doi.wiley.com/10.1002/chem.201302649
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MAGREZ-CHIQUET, Magaly et al. Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition. In: Chemistry - A European Journal, 2013, vol. 19, n° 41, p. 13663-13667. https://archive-ouverte.unige.ch/unige:30104

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Deposited on : 2013-10-02

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