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Scientific article
English

Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition

Published inChemistry, vol. 19, no. 41, p. 13663-13667
Publication date2013
Abstract

C-C coupling: DiPPAM 1 and BINAP 2 ligands led to divergent behaviors in the asymmetric conjugate addition (ACA) of dialkylzinc reagents to linear aryldienones, which were applied to the development of a highly selective sequential asymmetric 1,6/1,4-ACA process.

Keywords
  • Asymmetric synthesis
  • C—C coupling
  • Michael reaction
  • Stereoselective catalysis
Citation (ISO format)
MAGREZ-CHIQUET, Magaly et al. Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex-Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition. In: Chemistry, 2013, vol. 19, n° 41, p. 13663–13667. doi: 10.1002/chem.201302649
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ISSN of the journal0947-6539
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Technical informations

Creation10/01/2013 6:05:00 PM
First validation10/01/2013 6:05:00 PM
Update time03/14/2023 8:31:52 PM
Status update03/14/2023 8:31:52 PM
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