Catalysis with Anion-π Interactions

Zhao, Yingjie; Domoto, Yuya; Orentas, Edvinas; Beuchat, Cesar; Emery, Daniel; Mareda, Jiri; Sakai, Naomi; Matile, Stefan

doi:10.1002/anie.201305356

Scientific article

English

Catalysis with Anion-π Interactions

Contributors

Zhao, Yingjie; Domoto, Yuya; Orentas, Edvinas; Beuchat, Cesar; Emery, Daniel; Mareda, Jiri; Sakai, Naomi

; Matile, Stefan

Published in

Angewandte Chemie, vol. 52, no. 38, p. 9940-9943

Publication date

2013

Abstract

The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing π-acidity of the catalyst is observed; thus, anion–π interactions can contribute to catalysis.

Keywords

Kinetics
Molecular recognition
Noncovalent interactions
Organocatalysis
Transition states

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ZHAO, Yingjie et al. Catalysis with Anion-π Interactions. In: Angewandte Chemie, 2013, vol. 52, n° 38, p. 9940–9943. doi: 10.1002/anie.201305356

Article (Published version)

Article (Accepted version)

OA OTHER

Identifiers

PID : unige:29617
DOI : 10.1002/anie.201305356

Journal ISSN

1433-7851

740views

678downloads

Creation

13/09/2013 13:29:00

First validation

13/09/2013 13:29:00

Update

13/10/2025 23:26:01

Status update

14/03/2023 20:24:09

Last indexation

16/02/2026 06:57:04

Catalysis with Anion-π Interactions

Contributors

Published in

Publication date

Abstract

Keywords

UNIGE affiliation entities

Citation (ISO format)

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Journal ISSN

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Creation

First validation

Update

Status update

Last indexation