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Catalysis with Anion-π Interactions

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Published in Angewandte Chemie (International Edition). 2013, vol. 52, no. 38, p. 9940-9943
Abstract The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing π-acidity of the catalyst is observed; thus, anion–π interactions can contribute to catalysis.
Keywords KineticsMolecular recognitionNoncovalent interactionsOrganocatalysisTransition states
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ZHAO, Yingjie et al. Catalysis with Anion-π Interactions. In: Angewandte Chemie: International Edition, 2013, vol. 52, n° 38, p. 9940-9943. doi: 10.1002/anie.201305356 https://archive-ouverte.unige.ch/unige:29617

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Deposited on : 2013-09-16

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