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Scientific article
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English

Comparison of Lipoic and Asparagusic Acid for Surface-Initiated Disulfide-Exchange Polymerization

Published inChemistry, vol. 19, no. 35, p. 11558-11563
Publication date2013
Abstract

Bring it on: Organic chemistry on surfaces and in solution is not the same; this study offers a perfect example that small changes (from 27 to 35°; see graphic) can result in big consequences. Strained cyclic disulfides from asparagusic, but not lipoic acid, are ideal for growing functional architectures directly on surfaces; for the substrate-initiated synthesis of cell-penetrating poly(disulfide)s in solution, exactly the contrary is true.

Keywords
  • Covalent bonds
  • Disulfide exchange
  • Poly(disulfide)s
  • Polymerization
  • Surface chemistry
Citation (ISO format)
CARMINE, Alessio et al. Comparison of Lipoic and Asparagusic Acid for Surface-Initiated Disulfide-Exchange Polymerization. In: Chemistry, 2013, vol. 19, n° 35, p. 11558–11563. doi: 10.1002/chem.201301567
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Article (Published version)
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Article (Accepted version)
Identifiers
ISSN of the journal0947-6539
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Technical informations

Creation09/02/2013 4:58:00 PM
First validation09/02/2013 4:58:00 PM
Update time03/14/2023 8:23:53 PM
Status update03/14/2023 8:23:53 PM
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