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Comparison of Lipoic and Asparagusic Acid for Surface-Initiated Disulfide-Exchange Polymerization

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Published in Chemistry - A European Journal. 2013, vol. 19, no. 35, p. 11558-11563
Abstract Bring it on: Organic chemistry on surfaces and in solution is not the same; this study offers a perfect example that small changes (from 27 to 35°; see graphic) can result in big consequences. Strained cyclic disulfides from asparagusic, but not lipoic acid, are ideal for growing functional architectures directly on surfaces; for the substrate-initiated synthesis of cell-penetrating poly(disulfide)s in solution, exactly the contrary is true.
Keywords Covalent bondsDisulfide exchangePoly(disulfide)sPolymerizationSurface chemistry
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Other version: http://doi.wiley.com/10.1002/chem.201301567
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CARMINE, Alessio et al. Comparison of Lipoic and Asparagusic Acid for Surface-Initiated Disulfide-Exchange Polymerization. In: Chemistry - A European Journal, 2013, vol. 19, n° 35, p. 11558-11563. https://archive-ouverte.unige.ch/unige:29562

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Deposited on : 2013-09-04

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