Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

Jouaiti, Abdelaziz; Geoffroy, Michel; Terron, Gustavo; Bernardinelli, Gérald Hugues

doi:10.1039/C39920000155

Scientific article

English

Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

ContributorsJouaiti, Abdelaziz; Geoffroy, Michel; Terron, Gustavo; Bernardinelli, Gérald Hugues

Published inJournal of the Chemical Society. Chemical communications, no. 2, p. 155-156

Publication date1992

Abstract

A novel ligand containing two phosphaalkene moieties has been synthesized, which forms a palladium(II) complex whose crystal structure has been determined and whose reduction has been shown, by EPR spectroscopy, to take place on the ligand rather than on the metal.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Geoffroy

Citation (ISO format)

JOUAITI, Abdelaziz et al. Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups. In: Journal of the Chemical Society. Chemical communications, 1992, n° 2, p. 155–156. doi: 10.1039/C39920000155

Article (Published version)

Identifiers

PID : unige:2917
DOI : 10.1039/C39920000155

Journal ISSN0022-4936

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Synthesis, structure and ligand-centred reduction of an orthometallated complex of palladium containing two phosphaalkene groups

A novel ligand containing two phosphaalkene moieties has been synthesized, which forms a palladium(II) complex whose crystal structure has been determined and whose reduction has been shown, by EPR spectroscopy, to take place on the ligand rather than on the metal.

Technical informations