en
Scientific article
English

Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds

Published inOrganic letters, vol. 15, no. 15, p. 3930-3933
Publication date2013
Abstract

A direct nitrene insertion into C–N bonds is observed upon treatment of methano-Tröger bases with arylsulfonyl iminophenyliodinanes under copper and dirhodium catalysis. Novel cyclic imino-methano Tröger bases are obtained (55–88%). Enantiopure products (ee ≥ 99%) can be obtained with tailored substrates.

Citation (ISO format)
PUJARI, Sandip, GUENEE, Laure, LACOUR, Jérôme. Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds. In: Organic letters, 2013, vol. 15, n° 15, p. 3930–3933. doi: 10.1021/ol4016892
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal1523-7052
582views
6downloads

Technical informations

Creation08/02/2013 2:53:00 PM
First validation08/02/2013 2:53:00 PM
Update time03/14/2023 8:21:23 PM
Status update03/14/2023 8:21:23 PM
Last indexation01/16/2024 1:58:01 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack