Scientific article
English

Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds

Published in

Organic letters, vol. 15, no. 15, p. 3930-3933

Publication date

2013

Abstract

A direct nitrene insertion into C–N bonds is observed upon treatment of methano-Tröger bases with arylsulfonyl iminophenyliodinanes under copper and dirhodium catalysis. Novel cyclic imino-methano Tröger bases are obtained (55–88%). Enantiopure products (ee ≥ 99%) can be obtained with tailored substrates.

Citation (ISO format)

PUJARI, Sandip, GUENEE, Laure, LACOUR, Jérôme. Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds. In: Organic letters, 2013, vol. 15, n° 15, p. 3930–3933. doi: 10.1021/ol4016892

Main files (1)

Article (Published version)

Identifiers

Journal ISSN

1523-7052
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Technical informations

Creation

02/08/2013 14:53:00

First validation

02/08/2013 14:53:00

Update

14/03/2023 20:21:23

Status update

14/03/2023 20:21:23

Last indexation

30/10/2024 09:51:25
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