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Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds

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Published in Organic Letters. 2013, vol. 15, no. 15, p. 3930-3933
Abstract A direct nitrene insertion into C–N bonds is observed upon treatment of methano-Tröger bases with arylsulfonyl iminophenyliodinanes under copper and dirhodium catalysis. Novel cyclic imino-methano Tröger bases are obtained (55–88%). Enantiopure products (ee ≥ 99%) can be obtained with tailored substrates.
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Other version: http://pubs.acs.org/doi/abs/10.1021/ol4016892
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PUJARI, Sandip, GUENEE, Laure, LACOUR, Jérôme. Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds. In: Organic Letters, 2013, vol. 15, n° 15, p. 3930-3933. https://archive-ouverte.unige.ch/unige:29040

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Deposited on : 2013-08-05

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