NQR studies of polyhalocuprate(I) anions
|Published in||Inorganica Chimica Acta. 1994, vol. 227, no. 1, p. 153-157|
|Abstract||Attempts to prepare the tricyclohexylphosphine or triphenylstibine analogues of the recently reported (triphenylphosphine) CuX2− anions were unsuccessful and instead resulted in the formation of a variety of polyhalocuprate anions. The structure of one of these, [CH3P(C6H5)3]2Cu2I4, has been determined; monoclinic, P21/c; a = 16.715(3), b = 10.787(2), c = 23.196(3) Å, β=98.59(1)°, Z=4; R=6.3%, Rw=3.1%. The 63Cu NQR spectra of twelve such polyhalocuprate anions were observed and the results compared with those of previously reported polyhalocuprates.|
|Keywords||Crystal structures — Copper complexes — Halide complexes — Anion complexes|
This document has no fulltext available yet, but you can contact its author by using the form below.
|Research group||Groupe Lucken|
|RAMAPRABHU, Sundara et al. NQR studies of polyhalocuprate(I) anions. In: Inorganica Chimica Acta, 1994, vol. 227, n° 1, p. 153-157. https://archive-ouverte.unige.ch/unige:2876|