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Title

63Cu NQR spectra of dicoordinated Cu(I) cations with imidazole and pyrazole ligands

Authors
Motallebi, Shahrokh
Published in Journal of Molecular Structure. 1995, vol. 345, no. 1-3, p. 277-281
Abstract The 63Cu NQR spectra of five dicoordinated complex cations of Cu(I) with substituted imidazoles as ligands and six analogous complexes with substituted pyrazoles as ligands are reported. The structures of four of these complexes have been previously determined and the relationship of their 63Cu resonance frequency to the average Cu---N bond length is compared to that of the analogous lutidine or collidine complexes. It is concluded that there are probably significant differences between the electronic structures of the pyridine complexes and those of the pyrazole or imidazole series.
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Research group Groupe Lucken
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KHAJEHNOURI, Fereidoun, MOTALLEBI, Shahrokh, LUCKEN, Edwin-Anthony. 63Cu NQR spectra of dicoordinated Cu(I) cations with imidazole and pyrazole ligands. In: Journal of Molecular Structure, 1995, vol. 345, n° 1-3, p. 277-281. https://archive-ouverte.unige.ch/unige:2859

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Deposited on : 2009-09-21

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