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Title

Oxidation of a tricoordinated Cu-I complex to a tetracoordinated Cu-II species : a single-crystal EPR study

Authors
Palivan, Cornelia
Ramaprabhu, Sundara
Published in Journal of the Chemical Society Faraday Transactions. 1995, vol. 91, no. 14, p. 2155-2160
Abstract Bis(N-methylimidazolidinethi-2-one)copper(I) chloride has been synthesized and its crystal structure determined. X-Irradiation of a single crystal of this compound leads to the formation of a CuII complex which was studied by EPR: it was shown that this species results from the addition of a radiogenic Cl atom on the CuI precursor. The structural changes induced by this reaction are revealed by the g-tensor and by the hyperfine tensors of one copper and two chlorine nuclei. The structure of this S2Cl2Cu type complex was compared with other sulfur- or chlorine-containing CuII complexes.
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Research group Groupe Geoffroy
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PALIVAN, Cornelia et al. Oxidation of a tricoordinated Cu-I complex to a tetracoordinated Cu-II species : a single-crystal EPR study. In: Journal of the Chemical Society Faraday Transactions, 1995, vol. 91, n° 14, p. 2155-2160. https://archive-ouverte.unige.ch/unige:2858

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Deposited on : 2009-09-21

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