UNIGE document Scientific Article
previous document  unige:2844  next document
add to browser collection

Spin labelled C-glycoside analogs : derivatives of 1,4-anhydro-4-deoxy-2,3-O-cyclopentylidene-1,4-N-hydroxyimino-DL-erythrofuranose

Lichtle, Patrick
show hidden authors show all authors [1 - 9]
Published in Journal of Carbohydrate Chemistry. 1995, vol. 14, no. 1, p. 17-34
Abstract A series of 2,3-O-cyclopentylidene C-glycoside analogs in which the furanose ring has been replaced with a N-hydroxypyrrolidine have been prepared. A structural study of these tricyclic compounds and the aminoxyl radicals thereof has been carried out using variable temperature 1H NMR, X-ray diffraction, molecular dynamics and EPR spectroscopy. Both types of compounds, N-hydroxypyrrolidines and pyrrolidine N-oxyls, fundamentally prefer - in solutions- N-endo conformations over the alternate, N-exo forms found by X-ray diffraction studies and computed to be more stable by molecular dynamics.
Full text
This document has no fulltext available yet, but you can contact its author by using the form below.
Research group Groupe Geoffroy
(ISO format)
TRONCHET, Jean Marcel Julien et al. Spin labelled C-glycoside analogs : derivatives of 1,4-anhydro-4-deoxy-2,3-O-cyclopentylidene-1,4-N-hydroxyimino-DL-erythrofuranose. In: Journal of Carbohydrate Chemistry, 1995, vol. 14, n° 1, p. 17-34. doi: 10.1080/07328309508006434 https://archive-ouverte.unige.ch/unige:2844

457 hits

0 download


Deposited on : 2009-09-21

Export document
Format :
Citation style :