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Scientific article
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English

Spin-labelled glycolipid analogues : D-glucose series

Published inCarbohydrate research, vol. 275, no. 2, p. 245-258
Publication date1995
Abstract

Neoglycolipids bearing a paramagnetic probe in their lipophilic aglycon have been prepared. All belong to the Image -glucose series, both anomers for the glucoside representatives, respectively β and α anomers in the S- and C-glucosyl series. Two different types of radical sites have been used, a relatively short-lived imino N-oxyl group for glucosides and a more stable N-acylamino N-oxyl moiety in the other cases. EPR spectra of these radical species afforded information on the conformation of the lipophilic chain in the vicinity of the paramagnetic probe.

Keywords
  • EPR spectroscopy
  • Neoglycolipids
  • Spin labels
  • Glycosides
Research group
Citation (ISO format)
TRONCHET, Jean Marcel Julien, ZSELY SCHAFFTER, Martina Maria, GEOFFROY, Michel. Spin-labelled glycolipid analogues : D-glucose series. In: Carbohydrate research, 1995, vol. 275, n° 2, p. 245–258. doi: 10.1016/0008-6215(95)00177-U
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Article (Published version)
accessLevelPublic
Identifiers
ISSN of the journal0008-6215
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