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1,2-Bis[2,4,6-tri-tert-butylphenyl]phosphanediylmethyl]benzene, L : synthesis and structure of L, of the chelated complex [PdLCl2] and of a derived cyclometallated chiral complex

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Published in Chemical Communications. 1996, vol. 67, no. 3, p. 437-438
Abstract The synthesis and crystal structure of 1,2-bis[2-(2,4,6-tri-tert-butylphenyl)phosphanediylmethyl]benzene, L, are reported as well as the preparation and conformation of the novel seven-membered ring complex [PdLCl2]; this complex reacts with alcohols (MeOH, EtOH) to give a chiral cyclometallated complex [rac(R)P, (R)C; (S)P, (S)C] where the metal is bound to both a phosphaalkene and a phosphite phosphorus atom.
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Research group Groupe Geoffroy
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JOUAITI, Abdelaziz, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. 1,2-Bis[2,4,6-tri-tert-butylphenyl]phosphanediylmethyl]benzene, L : synthesis and structure of L, of the chelated complex [PdLCl2] and of a derived cyclometallated chiral complex. In: Chemical Communications, 1996, vol. 67, n° 3, p. 437-438. https://archive-ouverte.unige.ch/unige:2838

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