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Title

Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites

Authors
Collin, Jean-Paul
Published in Inorganica Chimica Acta. 1996, vol. 245, no. 1, p. 69-73
Abstract A bis-cyclometallating ligand bearing two different terdentate coordination sites (N---C---N: dipyridyI-benzene; P---C---P: diphosphaalkenebenzene moieties) has been synthesised. Selective reactions of appropriate metal complex precursors afforded a heterodinuclear ruthenium(II)-palladium(II) complex characterised by 1H, 13P NMR spectroscopy and FAB-MS techniques. We have compared its electrochemical and spectroscopic properties (absorption and emission) with the individual ruthenium(II) and palladium(II) subunits.
Keywords Ruthenium complexesPalladium complexesCyclometallated ligand complexesHeterodinuclear complexes
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Research group Groupe Geoffroy
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JOUAITI, Abdelaziz, GEOFFROY, Michel, COLLIN, Jean-Paul. Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites. In: Inorganica Chimica Acta, 1996, vol. 245, n° 1, p. 69-73. https://archive-ouverte.unige.ch/unige:2819

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