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English

Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites

Published inInorganica Chimica Acta, vol. 245, no. 1, p. 69-73
Publication date1996
Abstract

A bis-cyclometallating ligand bearing two different terdentate coordination sites (N---C---N: dipyridyI-benzene; P---C---P: diphosphaalkenebenzene moieties) has been synthesised. Selective reactions of appropriate metal complex precursors afforded a heterodinuclear ruthenium(II)-palladium(II) complex characterised by 1H, 13P NMR spectroscopy and FAB-MS techniques. We have compared its electrochemical and spectroscopic properties (absorption and emission) with the individual ruthenium(II) and palladium(II) subunits.

Keywords
  • Ruthenium complexes
  • Palladium complexes
  • Cyclometallated ligand complexes
  • Heterodinuclear complexes
Research group
Citation (ISO format)
JOUAITI, Abdelaziz, GEOFFROY, Michel, COLLIN, Jean-Paul. Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites. In: Inorganica Chimica Acta, 1996, vol. 245, n° 1, p. 69–73. doi: 10.1016/0020-1693(95)04799-9
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ISSN of the journal0020-1693
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