Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites

Jouaiti, Abdelaziz; Geoffroy, Michel; Collin, Jean-Paul

doi:10.1016/0020-1693(95)04799-9

Scientific article

English

Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites

Contributors

Jouaiti, Abdelaziz; Geoffroy, Michel; Collin, Jean-Paul

Published in

Inorganica Chimica Acta, vol. 245, no. 1, p. 69-73

Publication date

1996

Abstract

A bis-cyclometallating ligand bearing two different terdentate coordination sites (N---C---N: dipyridyI-benzene; P---C---P: diphosphaalkenebenzene moieties) has been synthesised. Selective reactions of appropriate metal complex precursors afforded a heterodinuclear ruthenium(II)-palladium(II) complex characterised by 1H, 13P NMR spectroscopy and FAB-MS techniques. We have compared its electrochemical and spectroscopic properties (absorption and emission) with the individual ruthenium(II) and palladium(II) subunits.

Keywords

Ruthenium complexes
Palladium complexes
Cyclometallated ligand complexes
Heterodinuclear complexes

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

UNIGE research groups

Groupe Geoffroy

Citation (ISO format)

JOUAITI, Abdelaziz, GEOFFROY, Michel, COLLIN, Jean-Paul. Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites. In: Inorganica Chimica Acta, 1996, vol. 245, n° 1, p. 69–73. doi: 10.1016/0020-1693(95)04799-9

Article (Published version)

Identifiers

PID : unige:2819
DOI : 10.1016/0020-1693(95)04799-9

Additional URL for this publication

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TG5-3TKNHPV-Y-1&_cdi=5245&_orig=browse&_coverDate=04%2F01%2F1996&_sk=997549998&view=c&wchp=dGLbVlz-zSkzS&_acct=C000043220&_version=1&_userid=779890&md5=ac8bb921b2ed664e29195b06f914ff4b&ie=f.pdf

Journal ISSN

0020-1693

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986downloads

Creation

21/09/2009 16:03:43

First validation

21/09/2009 16:03:43

Update

14/03/2023 15:12:05

Status update

14/03/2023 15:12:05

Last indexation

29/10/2024 12:02:40

Synthesis and characterisation of a heterodinuclear ruthenium(II)-palladium(II) complex with two different cyclometallating sites

Contributors

Published in

Publication date

Abstract

Keywords

UNIGE affiliation entities

UNIGE research groups

Citation (ISO format)

Main files (1)

Identifiers

Additional URL for this publication

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation