Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2
|Published in||Journal of Chemical Physics. 1997, vol. 106, no. 9, p. 3817-3820|
|Abstract||Laser flash photolysis experiments were performed on the mixed crystal [Zn1–xFex(6-mepy)3tren](PF6)2 (x=0.00025) at 10 K in the pressure range between 1 bar and 20 kbar. An external pressure of 20 kbar accelerates the low-temperature tunneling process by almost eight orders of magnitude.|
|Keywords||Zinc compounds — Iron compounds — Photolysis — High-pressure effects — Tunnelling|
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|Research group||Groupe Hauser|
|WANG, Wei et al. Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2. In: Journal of Chemical Physics, 1997, vol. 106, n° 9, p. 3817-3820. doi: 10.1063/1.473436 https://archive-ouverte.unige.ch/unige:2789|