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Scientific article
English

Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2

Published inThe Journal of chemical physics, vol. 106, no. 9, p. 3817-3820
Publication date1997
Abstract

Laser flash photolysis experiments were performed on the mixed crystal [Zn1–xFex(6-mepy)3tren](PF6)2 (x=0.00025) at 10 K in the pressure range between 1 bar and 20 kbar. An external pressure of 20 kbar accelerates the low-temperature tunneling process by almost eight orders of magnitude.

Keywords
  • Zinc compounds
  • Iron compounds
  • Photolysis
  • High-pressure effects
  • Tunnelling
Research group
Citation (ISO format)
WANG, Wei et al. Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2. In: The Journal of chemical physics, 1997, vol. 106, n° 9, p. 3817–3820. doi: 10.1063/1.473436
Identifiers
ISSN of the journal0021-9606
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