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Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2 |
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Authors | ||
Published in | The Journal of chemical physics. 1997, vol. 106, no. 9, p. 3817-3820 | |
Abstract | Laser flash photolysis experiments were performed on the mixed crystal [Zn1–xFex(6-mepy)3tren](PF6)2 (x=0.00025) at 10 K in the pressure range between 1 bar and 20 kbar. An external pressure of 20 kbar accelerates the low-temperature tunneling process by almost eight orders of magnitude. | |
Keywords | Zinc compounds — Iron compounds — Photolysis — High-pressure effects — Tunnelling | |
Identifiers | DOI: 10.1063/1.473436 | |
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Structures | ||
Research group | Groupe Hauser | |
Citation (ISO format) | WANG, Wei et al. Pressure effects on the HS -> LS relaxation in [Zn1-xFex(6-mepy)3tren](PF6)2. In: The Journal of chemical physics, 1997, vol. 106, n° 9, p. 3817-3820. doi: 10.1063/1.473436 https://archive-ouverte.unige.ch/unige:2789 |