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Isomerization of Terminal Epoxides by a [Pd–H] Catalyst: A Combined Experimental and Theoretical Mechanistic Study

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Published in Journal of the American Chemical Society. 2013, vol. 135, no. 16, p. 6177-6183
Abstract An unusual palladium hydride complex has been shown to be a competent catalyst in the isomerization of a variety of terminal and internal epoxides. The reaction displayed broad scope and synthetic utility. Experimental and theoretical evidence are provided for an unprecedented hydride mechanism characterized by two distinct enantio-determining steps. These results hold promise for the development of an enantioselective variant of the reaction.
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Other version: http://pubs.acs.org/doi/abs/10.1021/ja400325w
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VYAS, Devendra et al. Isomerization of Terminal Epoxides by a [Pd–H] Catalyst: A Combined Experimental and Theoretical Mechanistic Study. In: Journal of the American Chemical Society, 2013, vol. 135, n° 16, p. 6177-6183. https://archive-ouverte.unige.ch/unige:27608

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Deposited on : 2013-04-30

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