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Transmembrane Halogen-Bonding Cascades

Published in Journal of the American Chemical Society. 2013, vol. 135, no. 14, p. 5302-5303
Abstract Halogen bonds have recently been introduced as ideal to transport anions across lipid bilayer membranes. However, activities obtained with small transporters were not impressive, and cyclic arrays of strong halogen-bond donors above a calix[4]arene scaffold gave even weaker activities. Here, we report that their linear alignment for anion hopping along transmembrane rigid-rod scaffolds gives excellent activities with an unprecedented cooperativity coefficient m = 3.37.
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VARGAS JENTZSCH, Rodrigo Andreas, MATILE, Stefan. Transmembrane Halogen-Bonding Cascades. In: Journal of the American Chemical Society, 2013, vol. 135, n° 14, p. 5302-5303. doi: 10.1021/ja4013276 https://archive-ouverte.unige.ch/unige:27472

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Deposited on : 2013-04-10

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