Scientific article
English

Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones

Published inOrganic letters, vol. 15, no. 7, p. 1594-1597
Publication date2013
Abstract

Easily prepared alkenylalanates proved to be excellent nucleophiles for the creation of highly congested quaternary centers via copper-catalyzed conjugate addition. In addition, functionalized cis-decaline systems can now be prepared in a simple two-step sequence involving Cu-catalyzed conjugate addition with functionalized alkenylalanates.

Citation (ISO format)
MUELLER, Daniel, ALEXAKIS, Alexandre. Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones. In: Organic letters, 2013, vol. 15, n° 7, p. 1594–1597. doi: 10.1021/ol400378v
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accessLevelRestricted
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Journal ISSN1523-7052
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Creation05/04/2013 08:19:00
First validation05/04/2013 08:19:00
Update time14/03/2023 20:07:49
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