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Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones

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Published in Organic Letters. 2013, vol. 15, no. 7, p. 1594-1597
Abstract Easily prepared alkenylalanates proved to be excellent nucleophiles for the creation of highly congested quaternary centers via copper-catalyzed conjugate addition. In addition, functionalized cis-decaline systems can now be prepared in a simple two-step sequence involving Cu-catalyzed conjugate addition with functionalized alkenylalanates.
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Other version: http://pubs.acs.org/doi/abs/10.1021/ol400378v
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MUELLER, Daniel, ALEXAKIS, Alexandre. Creation of Highly Congested Quaternary Centers via Cu-catalyzed Conjugate Addition of Alkenyl Alanates to β-Substituted Cyclic Enones. In: Organic Letters, 2013, vol. 15, n° 7, p. 1594-1597. https://archive-ouverte.unige.ch/unige:27319

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Deposited on : 2013-04-08

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